Coordination Chemistry
Teacher
Dr Dojalisa Sahu
Category
Core Courses
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Course Name : Coordination Chemistry
Code(Credit) : CUTM1476(3-2-1)
Course Objectives
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To Know the basic of coordination chemistry, bio-inorganic chemistry and aimed at advanced knowledge in the field of industrial chemistry
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To be able to describe the stability of metal complexes by the use of formation constants and to calculate thermodynamic parameters from them
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To able to know the bonding and structure of coordination compounds and their applications in various field
Course Outcomes
| COs | Course outcomes | Mapping COs with POs (High-3, Medium-2, Low-1) |
| CO1 | The students will be able to demonstrate advanced knowledge and understanding in coordination compound | PO1(2) |
| CO2 | Understand the concepts of metal ligand bonding in transition complex compounds | PO2(3) |
| CO3 | Able to describe role of different metal ions in biological system | PO3(2) |
| CO4 | Able to recognize the biological reaction alkali and alkaline earth metals, nitrogen fixation, hemoglobin and myoglobin | PO4(2) |
| CO5 | Explain the role of Inorganic ―substances in living systems and the use of metal ions in medicinal therapy and diagnosis field | PO3(3) |
Course Syllabus
Module-I (7Hours)
Coordination Chemistry
Werner’s theory, Valence bond theory (inner and outer orbital complexes), Electro neutrality principle and back bonding.
Practice
· To Synthesis and Characterization of Metal Complexes with Schiff Base Ligands
· Estimation of nickel (II) using Dimethylglyoxime (DMG).
Module-II (11Hours)
Crystal Field Theory
Crystal field theory, measurement of 10 Dq (Δo), CFSE in weak and strong fields, pairing energies, factors affecting the magnitude of 10 Dq (Δo, Δt). Octahedral vs. tetrahedral coordination, tetragonal distortions from octahedral geometry Jahn-Teller theorem, square planar geometry. Qualitative aspect of Ligand field and MO Theory.
Practice
To familiar with the chromatographic method and its working principle
Module-III(8 Hours)
Nomenclature of Coordination Compounds
IUPAC nomenclature of coordination compounds, isomerism in coordination compounds. Stereochemistry of complexes with 4 and 6 coordination numbers. Chelate effect of polynuclear complexes, Labile and inert complexes.
Practice
· To Familiar with Kjeldahl apparatus and its operating procedure
Module-IV(11 Hours)
Transition Elements:
General group trends with special reference to electronic configuration, colour, variable valency, magnetic and catalytic properties, ability to form complexes. Stability of various oxidation states and e.m.f. (Latimer & Bsworth diagrams). Difference between the first, second and third transition series. Chemistry of Ti, V, Cr Mn, Fe and Co in various oxidation states (excluding their metallurgy)
Practice
· To estimate the amount of barium in the whole of the given solution of barium chloride
· Estimation of Iron in Hematite ore solution
Module-V (9hours )
Lanthanoids and Actinoids:
Electronic configuration, oxidation states, colour, Spectral and magnetic properties, lanthanide contraction, separation of lanthanides (ion-exchange method only),Actinides elements and properties
Practice
· To separate cation and anion from a unknown mixture by ion exchange column method
· Paper chromatographic separation of Ni(II) and Cu(II)
Module-VI(11Hours)
Bio-inorganic Chemistry-1:
Metal ions present in biological systems, classification of elements according to their action in biological system. Geochemical effect on the distribution of metals. Sodium / K-pump, Carbonic anhydrase and Carboxy peptidase. Excess and deficiency of some trace metals. Toxicity of metal ions (Hg, Pb, Cd and As), Reasons for toxicity, Use of chelating agents in medicine.
Practice
· To learn the working principle of colorimeter method
· Determination of Iron from a supplied waste water sample by redox and spectroscopic method
Module-VII(7Hours)
Bio-inorganic Chemistry-2:
Iron and its application in bio-systems, Hemoglobin, Storage and transfer of iron.
Project
Synthesis of ammine complexes of Ni(II) and its ligand exchange reactions (e.g. bidentate ligands like acetylacetone, DMG, glycine) by substitution method.
Recommended Books:
1. Purcell, K.F & Kotz, J.C. Inorganic ChemistryB. Saunders Co, 1977.
2. Huheey, J.E., Inorganic Chemistry, Prentice Hall, 1993.
3. Lippard, S.J. & Berg, J.M. Principles of Bioinorganic Chemistry Panima Publishing Company 1994.
4. Cotton, F.A. & Wilkinson, G, Advanced Inorganic Chemistry Wiley-VCH, 1999
5. Bassolo, F, and Pearson, R.C. Mechanisms of Inorganic Chemistry, John Wiley & Sons, NY, 1967.
6. Greenwood, N.N. & Earnshaw A. Chemistry of the Elements, Butterworth-Heinemann, 1997.
Recommended Books For Practice:
1.Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis 6th Ed., Pearson, 2009
Session Plan
Session 1
Werner's Theory, Isomerism and structure of Coordination Compound Limitation of Werner's theory
Session 2
Valence bond Theory ,Inner and outer orbital complexes
Youtube:https://www.youtube.com/watch?v=ft5yMiS-PyY
Slideshare:https://www.slideshare.net/itutor/valence-bond-theory-hybridization
Googledrive:https://drive.google.com/file/d/1pg2u9zawEm9kV0o3neJBUy66sVU6VAs3/view
Session 3(Practice-1)2 Hours
Estimation of Nickel(II) using Dimethylglyoxime(DMG)
Session 4
Electroneutrality principle and back bonding
Session 5(Practice 2) 2 Hours
To Synthesis and Characterization of Metal Complexes with Schiff Base Ligands
Session 6
Crystal field theory, measurement of 10 Dq (Δo)
Youtube:https://www.youtube.com/watch?v=8lT21wKoXyQ
Youtube:https://youtu.be/mAPFhZpnV58
https://www.youtube.com/watch?v=xTTgUcumYv0
Slideshare:https://www.slideshare.net/amnakhalid40/crystal-field-stabilization-energy-90300576
Session 7(Assignment-1:Flip Class) 1 Hours
To familiar with the chromatographic method and its working principle
https://www.youtube.com/watch?v=0m8bWKHmRMM
Session 8(Practice 3) 2 Hours
To Familiar with Kjeldahl apparatus and its operating procedure
Youtube:https://youtu.be/RqAywEa-Qss
Session 9
Factors affecting the magnitude of 10 Dq (Δo, Δt) in CFT
Youtube:https://www.youtube.com/watch?v=kyBb7ydc5Pk
Slideshare:https://www.slideshare.net/JawahirAli1/crystal-field-theory-99687563
Slideshare:https://www.slideshare.net/FARAZRANA2/factors-affecting-the-magnitude-of-o
Session 10
Octahedral vs. tetrahedral coordination of Crystal field theory
Youtube:https://youtu.be/baj0wf_4HXc
Slideshare:https://slideplayer.com/slide/1663325/
Session 11
Jahn-Teller theorem, square planar geometry
Youtube:https://www.youtube.com/watch?v=8ybR2zoNEg4
Slideshare:https://slideplayer.com/slide/4658727/
Session 12
Qualitative aspect of Ligand field Theory
Youtube:https://www.youtube.com/watch?v=4ronpqSzFNc
Slideshare:https://slideplayer.com/slide/5888178/
Session 13
Qualitative aspect of Molecular Orbital Theory
Youtube:https://www.youtube.com/watch?v=nTujP4jCbsg
Youtube:https://www.youtube.com/watch?v=HaUOu1kfG9E
Slideshare:https://www.slideshare.net/ZameerAhmedWassan/molecular-orbital-theory
Session 14(Practice 4) 2 Hours
To Preparation of Ferrous ammonium salt and estimation of Nitrogen
Session 15
IUPAC nomenclature of coordination compounds
Session -9-Nomenclature-Coordination Chemistry
Youtube:https://www.youtube.com/watch?v=KvobxSTHWE0
Youtube:https://www.youtube.com/watch?v=yeNtqjE0dJw
Slideshare:http://slideplayer.com/slide/1663289/
Session 16
Isomerism in coordination compounds
Session -10-Isomerism in Coordination Compound -Coordination Chemistry
Session 17(Assignment-2:Flip Class) 1 Hours
Stereo chemistry of complexes with 4 and 6 coordination numbers.
Youtube:https://www.youtube.com/watch?v=3d_rlA-pfeI
Slideshare:https://slideplayer.com/slide/10457491/
Session 18(Practice 5) 2 Hours
Preparation and Analysis of Potassium Trioxalatoferrate (III) Trihydrate
Session 19
Chelate effect of polynuclear complexes,
Youtube:https://www.youtube.com/watch?v=2maSuwf-VPY
Slideshare:https://slideplayer.com/slide/257864/
Session 20
Labile and inert complexes in coordination chemistry
Youtube:https://www.youtube.com/watch?v=uaFAMiGgQPk
Slideshare:https://slideplayer.com/slide/257864/
Session 21
General group trends with special reference to electronic configuration,
Youtube:https://youtu.be/akm5H2JsccI
Youtube:https://youtu.be/5CBs36jtZxY
Session 22
General group trends with special reference to colour, variable valency
Youtube:https://youtu.be/CCsNJFsYSGs
Youtube:https://youtu.be/akm5H2JsccI
Youtube:https://youtu.be/5CBs36jtZxY
Session 23(Practice 6) 2 Hours
To estimate of Iron in Haematite ore solution
Session 24(Assignment-3:Flip Class) 1 Hours
Explanation of Stability of various oxidation states and e.m.f.
Youtube:https://www.youtube.com/watch?v=EasDPvKCyXs
Slideshare:https://slideplayer.com/slide/4522367/
Session 25(Practice 7) 2 Hours
To estimate the amount of barium in the whole of the given solution of barium chloride
Session 26
Difference between the first, second and third transition series
Slideshare:https://www.slideshare.net/TakeenKhurshid/d-blockelements
Slideshare:https://www.slideshare.net/AvinashAvi110/comparative-study-of-d-block-elements
Session 27
Chemistry of Ti,V,Cr in various oxidation states (excluding their metallurgy)
Youtube:https://youtu.be/kCM2mSb4qIU
Youtube:https://youtu.be/n30yILpUitw
Slideshare:https://www.slideshare.net/e_gulfam/titinium
Slideshare:https://www.slideshare.net/sidrajaved2/transition-metals-and-complexes-vanadium-and-chromium-metal
Session 28
Chemistry of Mn,Fe in various oxidation states (excluding their metallurgy)
Youtube:https://www.youtube.com/watch?v=lIAmUx_vzfw
Slideshare:https://www.slideshare.net/sidrajaved2/transition-metals-and-complexes-vanadium-and-chromium-metal
Session 29(Assignment-4:Flip Class) 1 Hours
Chemistry of Co in various oxidation states (excluding their metallurgy)
Youtube:https://www.youtube.com/watch?v=3VvoO3-7Otw
Slideshare:https://slideplayer.com/slide/6241392/
Session 30
Lanthanoids:Electronic configuration, oxidation states, colour, spectral and magnetic properties,
Youtube:https://www.slideshare.net/pascchemistry/inner-transition-elements
Session 31
Lanthanide Contraction and its consequences
Youtube:https://www.youtube.com/watch?v=UpvFEizrNQU
Slideshare:https://www.slideshare.net/anikmal1/lanthanide-chemistry
Slideshare:https://www.slideshare.net/ssuserede232/f-block-element
Session 32(Assignment-5:Flip Class) 1 Hours
Actinides elements:Electronic configuration, oxidation states, colour, spectral and magnetic properties
Youtube:https://study.com/academy/lesson/actinide-series-elements-periodic-table.html
Slideshare:https://www.slideshare.net/puujipuuuj/actinide-series
Session 33
Separation Techniques of lanthanides (ion-exchange method only),Difference between lanthanides and Actinides
Youtube:https://www.youtube.com/watch?v=dblz6mnhu3k
Youtube:https://www.youtube.com/watch?v=OnV9kq6j3Tk
Youtube:https://www.youtube.com/watch?v=zPANzyDANFg
Slideplayers:https://slideplayer.com/slide/6817559/
Session 34(Practice 8) 2 Hours
To separate cation and anion from a unknown mixture by ion exchange column method
Session 35
Difference between lanthanides and Actinides
Youtube:https://www.youtube.com/watch?v=zPANzyDANFg
Slideplayers:https://slideplayer.com/slide/6817559/
Session 36(Practice 9) 2 Hours
Paper chromatographic separation of of Ni and Cu ion
Session 37
Metal ions present in biological systems,
Youtube:https://youtu.be/GTHWig1vOnY
Youtube:https://youtu.be/C_H-ONQFjpQ
Youtube:https://youtu.be/AkiaMiGnPuQ
Session 38(Assignment-6:Flip Class) 1 Hours
Classification of elements according to their action in biological system
Youtube:https://youtu.be/AkiaMiGnPuQ
Session 39
Sodium / K-pump in Biological System
Youtube:https://www.youtube.com/watch?v=_bPFKDdWlCg
Youtube:https://www.youtube.com/watch?v=7NY6XdPBhxo
Googledrive:https://drive.google.com/file/d/1jV1YPxhWNB1oHHfyRlvi-itM-PG7XlAq/view
Session 40(Assignments -7:Flip Class) 1 Hours
Geochemical effect on the distribution of metals
Youtube:https://www.slideshare.net/pramodgpramod/geochemical-cycle-and-mobility-of-elements-74268074
Slideshare:https://www.slideshare.net/LATIFHYDERWadho/geo-chemisty
Session 41
Chemistry of Carbonic anhydrase
Youtube:https://www.youtube.com/watch?v=7HR_b4t8c1k
Youtube:https://youtu.be/W5nLcHtuBvM
Slideshare:https://www.slideshare.net/SwaghathaAsokumar/bioinorganic-chemistry-49164874
Session 42
Chemistry of carboxy peptidase
Youtube:https://www.youtube.com/watch?v=7HR_b4t8c1k
Youtube:https://slideplayer.com/slide/9333477/
Slideshare:https://slideplayer.com/slide/12840018/
Slideshare:https://www.slideshare.net/SwaghathaAsokumar/bioinorganic-chemistry-49164874
Session 43(Practice 10) 2 Hours
Preparation and analysis of Lyophilic and Lyophobic Sols
Session 44
Excess and deficiency of some trace metals,Toxicity of metal ions Hg, reasons for toxicity
Youtube:https://www.youtube.com/watch?v=4LguFyBxGos
Youtube:https://www.youtube.com/watch?v=j29fF5nl2tM
Slideshare:https://slideplayer.com/slide/10803466/
Session 45(Assignment-8 :Flip Class) 1 Hours
Toxicity of metal ions Pb, reasons for toxicity
Youtube:https://www.youtube.com/watch?v=Ilw_HkR22GY
Youtube:https://www.youtube.com/watch?v=Egpy4y8cT38
Slideshare:https://slideplayer.com/slide/10803466/
Session 46
Toxicity of metal ions Cd,As,Fe, reasons for toxicity
Session 47
Toxicity of metal ions Cd,As,Fe, reasons for toxicity
Session 48(Assignment-9:Flip Class) 2 Hours
Notes on Use of chelating agents in medicine.
Youtube:https://slideplayer.com/slide/10303311/
Slideshare:https://www.slideshare.net/MinalSaini1/chelating-agents-and-its-application
Session 49(Practice 11) 2 Hours
Determination of Iron from a supplied waste water sample by redox method and spectroscopic method
Session 50
Hemoglobin and oxygen transport,
Youtube:https://youtu.be/LWtXthfG9_M
Youtube:https://youtu.be/QP8ImP6NCk8
Slideshare:https://www.slideshare.net/nileshkate79/haemoglobin-58248275
Slideplayers:https://slideplayer.com/slide/5682586/
Animation video :https://drive.google.com/file/d/1-sqlFcUyUHGxtzYTEzlCe6YKYzwsCIIk/view
Session 51(Assignment-10:Flip Class) 2 Hours
Storage and transfer of iron
Youtube:https://www.youtube.com/watch?v=498haH-rMVg
Youtube:https://slideplayer.com/slide/5778535/
Slideshare:https://www.slideshare.net/NikhilManoharan1/iron-storage-protein
Session 52(Practice 12) 2 Hours
Graphically compare the O2 affinity of hemoglobin and myoglobin
https://www.youtube.com/watch?v=Qv-KExGKAYw
http://:https://www.khanacademy.org/test-prep/mcat/biomolecules/enzyme-kinetics/v/cooperativity
Session 53
Iron and its application in bio-systems
Youtube:https://www.youtube.com/watch?v=JzOSC0DX1A0
Youtube:https://www.youtube.com/watch?v=riUHZn0xWRA
Slideshare:https://www.slideshare.net/NikhilManoharan1/iron-storage-protein
Slideplayers:https://slideplayer.com/slide/5682586/
Case Studies
Case Studies
Our Main Teachers
Dr Dojalisa Sahu
Associate Professor ,Department of Chemistry,School of Applied Sciences
VIEW PROFILEDr. Dojalisa Sahu completed her M.Sc. and M. Phil. degrees from Sambalpur University and joined CSIR-IMMT Bhubaneswar thereafter as a research assistant to peruse a career in research. She got her Ph.D. Degree awarded from Sambalpur University in 2014 and joined Centurion University of Technology and Management (CUTM) as an Assistant Professor in the School […]